Lihlahisoa

Hexafluoroisopropyl methyl ether (HFIPME) ke motsoako oa ether o tsitsitseng le o tsitsitseng ka lik'hemik'hale o nang le mefuta e mengata ea lisebelisoa likarolong tse sa tšoaneng.Hangata e sebelisoa e le mokelikeli, reagent, le ntho e sireletsang ka lebaka la thepa ea eona e ikhethang.E 'ngoe ea litšebeliso tse ka sehloohong tsa HFIPME ke sehlaseli liindastering tsa meriana le tsa lik'hemik'hale.Motsoako oa eona o babatsehang oa ho qhibiliha ka har'a metsoako ea tlhaho le ea tlhaho e etsa hore e be khetho e nepahetseng bakeng sa ho qhala mefuta e fapaneng ea lintho.HFIPME e thusa haholo bakeng sa ho qhala metsoako e nang le fluorinated haholo, li-peptide, le li-polymer tse itseng.Bokhoni ba eona ba ho qhibilihisa lisebelisoa tsena tse phephetsang bo etsa hore e be ea bohlokoa ho sibolloeng ha lithethefatsi, k'hemistri ea meriana, le polymer synthesis.Ho phaella ho thepa ea eona ea solvent, HFIPME e ka sebetsa e le reagent liketsong tse itseng.Ka mohlala, e ka sebelisoa ho khothalletsa maikutlo a ho felloa ke metsi 'meleng ka ho tlosa metsi ho tsoa metsoakong ea metsoako.HFIPME e boetse e na le bokhoni ba ho sebetsa joalo ka Lewis acid catalyst e bonolo, e tsamaisang likarabelo tse fapaneng joalo ka Friedel-Crafts acylation le cyclization reaction.Reactivity ea eona le khetho ea eona e etsa hore e be reagent e mengata ho organic synthesis.Ho feta moo, HFIPME e tsejoa ka bokhoni ba eona ba ho tsitsisa metsoako ea labile.E ka sebetsa e le moemeli ea sireletsang ho thibela ho senyeha kapa oxidation ea lintho tse bonolo nakong ea polokelo kapa mekhoa ea ho itšoara.Sena se bohlokoa haholo bakeng sa ho tsitsisa li-intermediate tse sebetsang, ho sireletsa lihlopha tse sebetsang, le ho boloka botšepehi ba limolek'hule tse tetemang.Thepa ea HFIPME ea ho tsitsisa e etsa hore e be ea bohlokoa mafapheng a meriana, agrochemicals, le mahlale a thepa.Tsebeliso e 'ngoe e hlokomelehang ea HFIPME ke tšebeliso ea eona e le motsoako oa cryogenic.Ka lebaka la ho belisa ha eona ho tlase (-24.7 ° C), e ka sebelisoa ho latela maemo a mocheso o tlase.HFIPME's cryogenic nature e etsa hore e khone ho sebelisoa mafapheng a kang cryobiology, cryo-electron microscopy, le superconductivity research.Ho feta moo, HFIPME e bontšitse bokhoni lefapheng la khemistri ea analytical, haholo-holo ho nuclear magnetic resonance (NMR) spectroscopy.E le solvent, e na le palo e tlase ea proton, viscosity e tlase, le litšobotsi tse ntle tsa ho qhibiliha, e e etsa khetho e nepahetseng bakeng sa tlhahlobo ea NMR.HFIPME e atisa ho khethoa bakeng sa ho ithuta lisampole tse thata, tse kenyelletsang li-peptide, liprotheine, le lihlahisoa tsa tlhaho.Thepa ea eona ea solvent, reactivity, liphello tse tsitsitseng, tlhaho ea cryogenic, le ho lumellana le tlhahlobo ea NMR e etsa hore e be ea bohlokoa lits'ebetsong tse fapaneng tsa saense le tsa indasteri.Ho tloha ho motsoako oa meriana ho ea ho cryobiology, HFIPME e bapala karolo ea bohlokoa mafapheng a 'maloa.