Lihlahisoa

Setšoantšo sa spectroscopy se matlafalitsoeng ka makhetlo a mararo ka mokhoa o matla oa maqhubu a mane se sebelisoa ho bona phetisetso ea momahano ea thothomelo lipakeng tsa mekhoa ea CO-otlolla ea asymmetric le symmetric CO-stretching ea rhodium(I) dicarbonyl acetylacetonate (RDC).Phetisetso e momahano ke phetoho e se nang mahlaseli ea boemo bo holimo bo kopaneng ba linaha tsa quantum ho ea ho maemo a holimo a momahaneng a fapaneng ka lebaka la ho kopanngoa ha mekhoa ea ho thothomela ka bateng.Li-pulse tse tharo tse hlasimollang tekong li lumellana le ho lumellana ha quantum e le 'ngoe, empa ho fetisa momahano ho fella ka likamano tse ncha tse nang le maqhubu a fapaneng.Maqhubu a macha a hlahisoang a bonoa ka monochromator e e rarollang ho tloha tlhorong e matla ea maqhubu a pele a ho hlasimolla.Mokhoa ona o rarolla ka mokhoa o hlakileng litsela tse kenyelletsang phetiso e lumellanang, e khethollang likarolo tsa spectral tse entsoeng feela ke liphetoho tsa mahlaseli, 'me ka nakoana e rarolla liphetoho tse entsoeng ke ho kena-kenana pakeng tsa litsela tse fapaneng tsa ho tsamaisana.Theory ea Redfield simulizi e lieha ho feto-fetoha ha nakoana moeling o potlakileng, empa ho boetse ho hlakile hore phetisetso ea tumellano e tlola karohano ea lefatše e hlahisitsoeng ke likhopolo tse ngata tsa Redfield.Ho e-na le hoo, e hloka liphello tse seng tsa Markovian le tsa ho hlapa.RDC e ka fana ka mohlala o bonolo bakeng sa nts'etsopele ea likhopolo tse kenyelletsang litlamorao tsena.